Voltammetric Behavior of Ruthenium Oxide in Organic Electrolyte Containing Imidazolium Salt
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چکیده
منابع مشابه
Voltammetric Behavior of Bilirubin Based on [bmim][PF6] As the Supporting Electrolyte in Organic Solvent and Its Analytical Application
The electrochemical oxidation behaviors of bilirubin (BR) at the bare glassy carbon electrode (GCE) were studied in dimethyl formamide (DMF) containing 1 vol.% of 1-butyl-3-methylimidazolium hexafluorophosphate ([bmim][PF6]) as the supporting electrolyte. Some electrochemical parameters of BR oxidation were investigated by cyclic voltammetry and chronocoulometry. The oxidation products were ide...
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The AgBr and Ag(2)Se nanoparticles (NPs) have been synthesized for the first time from two single source precursors ([Ag(2)(L)(2)Br(2)] (1) and [Ag(L-HBr)(2)]BF(4) (2) respectively) designed using the same ligand 3-benzyl-1-(2-phenylselanyl-ethyl)-3H-imidazolium bromide (L). The ODE-ODA-OA (1 : 1 : 2) and TOP-OA (1 : 2) are most suitable solvents for thermolysis of 1 and 2 respectively, resulti...
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در این پروژه ترکیبات 3-آریل-2h-بنزو[b]-4،1-اکسازین ها از مواد اولیه تجاری مشتقات دو آمینو فنول و ?-هالو کتون های آروماتیک در مایع یونی 1-اکتیل-3-متیل ایمیدازولیوم تترا فلورو بورات([omim]bf4) سنتز شده است. این واکنش توسط باز پتاسیم کربنات محلول از طریق o-آلکیلاسیون و سپس یک واکنش آمیداسیون درون مولکولی خود بخود در مدت زمان کوتاه انجام می شود. ترکیبات 4،1-بنزوکسازین به این روش با بهره خوب تا آلی ...
15 صفحه اولRuthenium catalysis in organic synthesis*
Ruthenium, rhodium, iridium, and rhenium hydride complexes are highly useful redox Lewis acid and base catalysts. Various substrates bearing hetero atoms are activated by these catalysts and undergo reactions with either nucleophiles or electrophiles under neutral conditions. These types of catalytic reactions are described together with their application to the preparation of various biologica...
متن کاملVoltammetric Investigations of Natural Organic Matter
Redox activity is one of the most important, and yet poorly understood, properties of natural organic matter (NOM). It is well known that NOM can act as a reducing agent (reductant), and this is central to the role that NOM plays in the biogeochemical cycling of carbon. More recently, there has been growing interest in the role that NOM plays as an electron shuttle (mediator) in biogeochemical ...
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ژورنال
عنوان ژورنال: Electrochemistry
سال: 2007
ISSN: 2186-2451,1344-3542
DOI: 10.5796/electrochemistry.75.595